KTP
KTP
KTP
KTP
KTP
KTP
KTP

Potassium Titanyl Phosphate (KTiOPO3 or KTP) is widely used in both commercial and military lasers including laboratory and medical systems, range-finders, lidar, optical communication and industrial systems.


Table 1. Chemical and Structural properties

Crystal Structure

Orthorhombic, space group Pna21,point group mm2

Lattice Parameter

a=6.404?, b=10.616?, c=12.814?, Z=8

Melting Point   

About 1172°C

Mohs Hardness   

5

Density         

3.01 g/cm3

Thermal Conductivity  

13W/m/K

Thermal Expansion Coefficient

αx=11x10-6/°C, αy=9x10-6/°C, αz=0.6x10-6/°C


Table 2. Optical and Nonlinear Optical Properties

Transparency Range

350~4500nm

SHG Phase Matchable Range

497~1800nm  (Type II)

Therm-optic Coefficients
(/°C)

dnx/dT=1.1X10-5
dny/dT=1.3X10-5
dnz/dT=1.6X10-5

Absorption  Coefficients

<0.1%/cm at 1064nm    <1%/cm at 532nm

For Type II SHG of a Nd:YAG laser at 1064nm

 

 

Temperature Acceptance: 24°C-cm
Spectral Acceptance: 0.56nm-cm
Angular Acceptance: 14.2mrad-cm (φ);55.3mrad-cm (θ)
Walk-off Angle: 0.55°

NLO Coefficients

deff(II)≈(d24-d15)sin2φsin2θ-(d15sin2φ + d24cos2φ)sinθ

Non-vanished NLO susceptibilities

d31=6.5 pm/V    d24=7.6 pm/V
d32=5 pm/V        d15=6.1 pm/V
d33=13.7 pm/V

Sellmeier  Equations
(λ in μm)     

nx2=3.0065+0.03901/(λ2-0.04251)-0.01327λ 2
ny2=3.0333+0.04154/(λ 2-0.04547)-0.01408λ2
nz2=3.3134+0.05694/(λ 2-0.05658)-0.01682λ2

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