BIBO( BiB3O6) is a newly developed nonlinear Optical Crystal. It possesses large effective nonlinear coefficient,high damage threshold and inertness with respect to moisture. Its nonlinear coefficient is 3.5-4 times higher than that of LBO, 1.5-2 times higher than that of BBO. It is a promising doubling crystal to produce blue laser.
Specifications
· Dimension tolerance: (W±0.1mm)x(H±0.1mm)x(L+0.5/-0.1mm) (L≥2.5mm)
(W±0.1mm)x(H±0.1mm)x(L+0.1/-0.1mm) (L<2.5mm)
· Clear aperture: central 90% of the diameter
· Flatness: less than λ/8 @ 633nm
· Transmitting wavefront distortion: less than λ/8 @ 633nm
· Chamfer: ≤0.2mmx45°
· Chip: ≤0.1mm
· Scratch/Dig code: better than 10/ 5 to MIL-PRF-13830B
· Parallelism: better than 20 arc seconds
· Perpendicularity: ≤5 arc minutes
· Angle tolerance: Δθ≤0.25°, ΔΦ≤0.25°
· Damage threshold[GW/cm2 ]: >0.3 for 1064nm, TEM00, 10ns, 10HZ
· Quality Warranty Period: one year under proper use.
Table 1.Chemical and Structural properties
Crystal Structure | Monoclinic,Point group 2 |
Lattice Parameter | a=7.116Å, b=4.993Å, c=6.508Å, β=105.62° ,Z=2 |
Melting Point | 726°C |
Mohs Hardness | 5-5.5 |
Density | 5.033 g/cm3 |
Thermal Expansion coefficient | αa=4.8x10-5/K, αb=4.4x10-6/K, αc=-2.69x10-5/K |
Table 2. Optical and Nonlinear Optical properties
Transparency Range | 286-2500nm |
Absorption Coefficient | <0.1%/cm at 1064nm |
Physical Axis | X//b,(Z,a)=31.6°,(Y,c)=47.2° |
SHG of 1064/532 | Phase matching angle:168.9° from z axis in YZ plane |
Sellmeier coefficients | ni2(λ)=A+B / (λ2-C)-Dλ2 (λ in um) | |||
A | B | C | D | |
n1 | 3.6545(4) | 0.0511(2) | 0.0371(3) | 0.0226(1) |
n2 | 3.0740(3) | 0.0323(1) | 0.0316(3) | 0.01337(6) |
n3 | 3.1685(3) | 0.0373(1) | 0.0346(3) | 0.01750(8) |